JEE Main 2023 Chemistry Syllabus

JEE Main Chemistry Syllabus 2023

JEE Main Chemistry Syllabus is available for free for all candidates on the Extramarks website. This is the latest JEE Main Chemistry syllabus specified by the National Testing Agency (NTA). Students preparing for JEE Main should check out the latest JEE Main Chemistry syllabus and create a robust and effective preparation strategy for scoring high in Chemistry. 

Extramarks is a single place to get updates about JEE Main 2023. You can get all the information about the JEE Main exam – JEE Main registration, JEE Main application form, JEE Main exam dates, JEE Main syllabus, JEE Main admit card, JEE Main cutoff from previous years, etc.

Introduction to JEE Main:

JEE (Joint Entrance Examination) is a crucial exam and the first step that helps engineering aspirants become eligible for undergraduate engineering courses. Moreover, it is also a qualifying exam for JEE Advanced. It is conducted online and is now held as a computer-based test (CBT). Students of classes 11 and 12 start preparing for the exam. Cracking JEE Main helps get admission into IITs, NITs, CFTIs. 

JEE Main is known to be one of the toughest entrance exams globally. Yearly there are lakhs of candidates appearing for this test across India. The most suitable process for JEE Main preparation is to have a very clear understanding of the syllabus, access all suitable study material, and prepare for the exams by solving multiple question papers and revising regularly. Extramarks is the go-to reference website for students preparing for JEE Main and JEE Advanced exams. Students will get free resources about JEE Main question papers, JEE advanced question papers, JEE Main sample papers, JEE Main revision notes, JEE Main mock tests, and many other study reference materials.

JEE Main Chemistry Syllabus – Overview

Most students consider Chemistry as the most scoring subject In JEE Main examination. Chemistry questions are mostly moderate level or easy, primarily based on fundamental concepts. Hence, students who have mastery over the NCERT curriculum and have an excellent command of their basics do well in the Chemistry section. Questions in this subject are primarily theoretical and based on fundamentals. Also, there are fewer numericals, so it is quicker for students. 

Chemistry questions are not calculation-based but primarily depend on theory and sound fundamentals. Hence, students can answer these correctly and in much less time than the other two subjects. Chemistry questions are mainly asked from the NCERT 11th and 12th textbooks and the NCERT 11th and 12th exemplar books.

Students should thoroughly go through the JEE Main Chemistry syllabus and have a study plan covering all chapters and topics, including the revision time. They should know all the formulae, reactions, equations, and periodic tables as they are essential to answering the questions. 

Out of the three subjects for JEE Main, Chemistry is considered the most straightforward section in which students can score good marks. Experts recommend attempting Chemistry in the JEE Main exam, then either Mathematics or Physics.

JEE Main Chemistry Syllabus – Subject wise 

The JEE Chemistry syllabus is based on 11th and 12th class subjects from NCERT textbooks.

All chapters are divided into – Physical Chemistry, Inorganic Chemistry and Organic Chemistry and they have equal weightage.

Section Chapters
Physical Chemistry Some Basic Concepts in Chemistry
Atomic Structure
State of Matter
Chemical Bonding and Molecular Structure
Chemical Thermodynamics
Solutions
Equilibrium
Redox, Reaction and Electrochemistry
Chemical Kinetics
Surface Chemistry
Inorganic Chemistry Classification of elements and periodicity in properties
Hydrogen
Block elements (alkali and alkaline earth metals)
P Block elements group 13 to group 18 elements.
d- and f – block elements
Coordination compounds
Environmental Chemistry
General principles and processes of isolation of metals
Organic Chemistry Purification and characterisation of organic compounds
Hydrocarbons
Chemistry in everyday life
Principles related to practical chemistry
Organic compounds containing –

  • Halogens
  • Oxygen
  • Nitrogen
Polymers
Biomolecules
Some basic principles of organic chemistry

JEE Main Chemistry Syllabus – Physical Chemistry

The JEE Main Chemistry Syllabus for Physical Chemistry is as follows:

Chapter 1 – Some Basic Concepts of Chemistry

  • Matter and its nature, Dalton’s atomic theory, the concept of the atom, molecule, element, and compound.
  • Physical quantities and their measurements in Chemistry, precision, accuracy, significant figures, S.I. Units, dimensional analysis.
  • Laws of chemical combination.
  • Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae.
  • Chemical equations and stoichiometry.

Chapter 2 – States of Matter

    • Classification of matter into solid, liquid, and gaseous states.
    • Gaseous State: Measurable properties of gases; Gas laws – Boyle’s law, Charles’s law, Graham’s law of diffusion, Avogadro’s Law, Dalton’s Law of partial pressure.
    • The concept of the Absolute scale of temperature; Ideal gas equation, Kinetic theory of gases (only postulates).
    • The concept of average, root mean square and most probable velocities.
    • Real gases, deviation from Ideal behaviour, compressibility factor, van der Waals equation, liquefaction of gases, critical constants.
    • Liquid State: Properties of liquids – vapour pressure, viscosity and surface tension and effect of temperature on them (qualitative treatment only).
    • Solid State: Classification of solids-molecular, ionic, covalent, and metallic solids, amorphous and crystalline solids (elementary idea).
    • Bragg’s Law and its applications.
  • Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell parameters, imperfection in solids. 
  • Electrical, magnetic, and dielectric properties

Chapter 3 – Atomic Structure

  • Discovery of subatomic particles (electron, proton, and neutron).
  • Thomson and Rutherford atomic models and their limitations.
  • Nature of electromagnetic radiation, the photoelectric effect.
  • The spectrum of hydrogen atoms, Bohr model of hydrogen atom – its postulates, derivation of the relations for the energy of the electron and radii of the different orbits, limitations of Bohr’s model.
  • Dual nature of matter, de-Broglie relationship, Heisenberg uncertainty principle.
  • Elementary ideas of quantum mechanics, the quantum mechanical model of an atom, its important features, the concept of atomic orbitals as one-electron wave functions.
  • Variation of Ψ1 and Ψ2 with r for 1s and 2s orbitals; various quantum numbers (principal, angular momentum, and magnetic quantum numbers), and their significance.
  • Shapes of s, p and d – orbitals, electron spin and spin quantum number.
  • Rules for filling electrons in orbitals – Aufbau principle, Pauli exclusion principle and Hund’s rule, electronic configuration of elements, the extra stability of half-filled and filled orbitals.

Chapter 4 – Chemical Bonding and Molecular Structure

  • Kossel – Lewis approach to chemical bond formation, the concept of ionic and covalent bonds.
  • Ionic Bonding: Formation of ionic bonds, factors affecting the formation of ionic bonds; calculation of lattice enthalpy.
  • Covalent Bonding: Concept of electronegativity, Fajan’s rule, dipole moment; Valence Shell Electron Pair Repulsion (VSEPR) theory and shapes of simple molecules.
  • Quantum mechanical approach to covalent bonding: Valence bond theory, its important features, the concept of hybridisation involving s, p, and d orbitals; Resonance.
  • Molecular Orbital Theory: Its important features, LCAOs, types of molecular orbitals (bonding, antibonding), sigma and pi-bonds, molecular orbital electronic configurations of homonuclear diatomic molecules, the concept of bond order, bond length and bond energy.
  • Elementary idea of metallic bonding, Hydrogen bonding, and its applications

Chapter 5 – Chemical Thermodynamics

    • Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes.
    • First Law of thermodynamics: Concept of work, internal heat energy, enthalpy, heat capacity, molar heat capacity.
    • Hess’s Law of constant heat summation.
  • Enthalpies of bond dissociation, combustion, formation, atomisation, sublimation, phase transition, hydration, ionisation, and solution.
  • The Second Law of thermodynamics: Spontaneity of processes; Delta S of the universe and Delta G of the system as criteria for spontaneity, Delta Go (Standard Gibbs energy change) and equilibrium constant.

Chapter 6 – Solutions

    • Different methods for expressing the concentration of a solution: molality, molarity, mole fraction, percentage (by volume and mass both), the vapour pressure of solutions and Raoult’s Law.
    • Ideal and non-ideal solutions, vapour pressure – composition, plots for ideal and non-ideal solutions.
    • Colligative properties of dilute solutions, relative lowering of vapour pressure, depression of freezing point, the elevation of boiling point and osmotic pressure.
    • Determination of molecular mass using colligative properties.
  • Abnormal value of molar mass, Hoff factor, and its significance.

Chapter 7 – Equilibrium

    • Meaning of equilibrium, the concept of dynamic equilibrium.
    • Equilibria involving physical processes: Solid-liquid, liquid – gas and solid-gas equilibria, Henry’s Law, a general characteristic of equilibrium involving physical processes.
    • Equilibria involving chemical processes: Law of chemical equilibrium, equilibrium constants (Kp and Kc) and their significance, the significance of Delta G and Delta Go in chemical equilibria, factors affecting equilibrium concentration, pressure, temperature, the effect of the catalyst.
  • Le Chatelier’s principle. 
  • Ionic equilibrium: Weak and strong electrolytes, ionisation of electrolytes, various concepts of acids and bases (Arrhenius, Bronsted-Lowry, and Lewis) and their ionisation, acid-base equilibria (including multistage ionisation) and ionisation constants, ionisation of water, pH scale, common ion effect, hydrolysis of salts and pH of their solutions, the solubility of sparingly soluble salts and solubility products, buffer solutions.

Chapter 8 – Redox Reactions and Electrochemistry

    • Electronic concepts of oxidation and reduction, redox reactions, oxidation number, rules for assigning oxidation number, balancing of redox reactions.
    • Electrolytic and metallic conduction, conductance in electrolytic solutions, specific and molar conductivities, and their variation with concentration.
    • Kohlrausch’s Law and its applications.
    • Electrochemical cells: Electrolytic and Galvanic cells, different types of electrodes, electrode potentials including standard electrode potential, half–cell and cell reactions, emf of a Galvanic cell and its measurement.
    • Nernst equation and its applications; Relationship between cell potential and Gibbs’ energy change.
  • Dry cell and lead accumulator, Fuel cells.
  • Corrosion and its prevention.

Chapter 9 – Chemical Kinetics

    • The rate of a chemical reaction, factors affecting the rate of reactions: concentration, temperature, pressure, and catalyst.
    • Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units, differential, and integral forms of zero and first-order reactions, their characteristics and half-lives, the effect of temperature on the rate of reactions.
  • Arrhenius theory, activation energy and its calculation, collision theory of bimolecular gaseous reactions (no derivation).

Chapter 10 – Surface Chemistry

  • Adsorption: Physisorption and chemisorption and their characteristics, factors affecting the adsorption of gases on solids: Freundlich and Langmuir adsorption isotherms, adsorption from solutions.
  • Catalysis: Homogeneous and heterogeneous, activity and selectivity of solid catalysts, enzyme catalysis, and its mechanism.
  • Colloidal state: Distinction among true solutions, colloids, and suspensions, classification of colloids: lyophilic, lyophobic.
  • Multimolecular, macromolecular and associated colloids (micelles), Preparation and properties of colloids: Tyndall effect, Brownian movement, electrophoresis, dialysis, coagulation, and flocculation. 
  • Emulsions and their characteristics.

JEE Main Chemistry Syllabus – Inorganic Chemistry

The JEE Main Chemistry Syllabus for Inorganic Chemistry is as follows:

Chapter 11 – Classification of Elements and Periodicity in Properties

    • Modern Periodic Law and the present form of the periodic table.
    • S, p, d and f block elements.
  • Periodic trends in properties of elements atomic and ionic radii, ionisation enthalpy.
  • Electrons gain enthalpy, valence, oxidation states and chemical reactivity.

Chapter 12 – General Principles and Process of Isolation of Metals

    • Modes of occurrence of elements in nature, minerals, ores.
  • Steps involved in the extraction of metals: concentration, reduction (chemical and electrolytic methods) and refining with special reference to the extraction of Al, Cu, Zn, and Fe. 
  • Thermodynamic and electrochemical principles are involved in the extraction of metals.

Chapter 13 – Hydrogen

    • The position of Hydrogen in the periodic table, isotopes, preparation, properties, and uses of Hydrogen.
    • Physical and chemical properties of water and heavy water.
    • Structure, preparation, reactions, and uses of hydrogen peroxide.
  • Classification of hydrides: ionic, covalent, and interstitial. 
  • Hydrogen as a fuel.

Chapter 14 – sBlock Elements (Alkali and Alkaline Earth Metals)

    • Group 1 and Group 2 Elements: General introduction, electronic configuration, general trends in physical and chemical properties of elements, anomalous properties of the first element of each group, diagonal relationships.
    • Preparation and properties of some important compounds: sodium carbonate, sodium chloride, sodium hydroxide and sodium hydrogen carbonate.
  • Industrial uses of lime, limestone, Plaster of Paris, and cement. 
  • The biological significance of Na, K, Mg, and Ca.

Chapter 15 – p Block Elements

    • Group 13 to Group 18 Elements: General Introduction, Electronic configuration, and general trends in physical and chemical properties of elements across the periods and down the groups; unique behaviour of the first element in each group. Groupwise study of the p block elements.
    • Group 13: Preparation, properties, and uses of boron and aluminium; Structure, properties and uses of borax, boric acid, diborane, boron trifluoride, aluminium chloride, and alums.
    • Group 14: Tendency for catenation; Structure, properties, and uses of allotropes and oxides of carbon, silicon tetrachloride, silicates, zeolites, and silicones.
    • Group 15: Properties and uses of nitrogen and phosphorus; Allotropic forms of phosphorus; Preparation, properties, structure, and uses of ammonia, nitric acid, phosphine, and phosphorus halides (PCl3, PCl5); Structures of oxides and oxoacids of nitrogen and phosphorus.
    • Group 16: Preparation, properties, structures and uses of dioxygen and ozone; Allotropic forms of sulphur; Preparation, properties, structures, and uses of sulphur dioxide, sulphuric acid (including its industrial preparation); Structures of oxoacids of sulphur.
  • Group 17: Preparation, properties, and uses of chlorine and hydrochloric acid; Trends in the acidic nature of hydrogen halides; Structures of Interhalogen compounds and oxides and oxyacids of halogens. 
  • Group 18: Occurrence and uses of noble gases; Structures of fluorides and oxides of xenon.

Chapter 16 – d and f Block Elements

    • Transition Elements: General introduction, electronic configuration, occurrence and characteristics, general trends in properties of the first-row transition elements: physical properties, ionisation enthalpy, oxidation states, atomic radii, colour, catalytic behaviour, magnetic properties, complex formation, interstitial compounds, alloy formation.
  • Preparation, properties, and uses of K2Cr2O7 and KMnO4. 
  • Inner Transition Elements: Lanthanides, Electronic configuration, oxidation states, chemical reactivity and lanthanide contraction, and Actinoids: Electronic configuration and oxidation states.

Chapter 17 – Coordination Compounds

    • Introduction to coordination compounds, Werner’s theory.
    • Ligands, coordination number, denticity, chelation.
    • IUPAC nomenclature of mononuclear coordination compounds, isomerism.
  • Bonding-Valence bond approach and basic ideas of Crystal field theory, colour and magnetic properties. 
  • Importance of coordination compounds (in qualitative analysis, extraction of metals and in biological systems).

Chapter 18 – Environmental Chemistry

    • Environmental pollution: Atmospheric, water, and soil.
    • Atmospheric pollution: Tropospheric and stratospheric.
    • Gaseous pollutants: Oxides of carbon, nitrogen, and sulphur, hydrocarbons; their sources, harmful effects, and prevention.
    • Greenhouse effect and Global warming, acid rain.
    • Particulate pollutants: Smoke, dust, smog, fumes, mist; their sources, harmful effects, and prevention.
    • Stratospheric pollution: Formation and breakdown of ozone, depletion of the ozone layer, its mechanism, and effects.
    • Water Pollution: Major pollutants such as pathogens, organic wastes, and chemical pollutants; their harmful effects and prevention.
  • Soil pollution: Major pollutants such as Pesticides (insecticides, herbicides, and fungicides) their harmful effects and prevention. 
  • Strategies to control environmental pollution.

JEE Main Chemistry Syllabus  – Organic Chemistry

The JEE Main Chemistry Syllabus for Inorganic Chemistry is as follows:

Chapter 19 – Purification and Characterisation of Organic Compounds

    • Purification: Crystallisation, sublimation, distillation, differential extraction, and chromatography principles and their applications.
    • Qualitative analysis: Detection of nitrogen, sulphur, phosphorus, and halogens.
  • Quantitative analysis (basic principles only): Estimation of carbon, Hydrogen, nitrogen, halogens, sulphur, phosphorus.
  • Calculations of empirical formula and molecular formulae; Numerical problems in organic quantitative analysis

Chapter 20 – Some Basic Principles of Organic Chemistry

    • Tetravalency of carbon; Shapes of simple molecules – hybridisation (s and p).
    • Classification of organic compounds based on functional groups: -C = C- and those containing halogens, oxygen, nitrogen, and sulphur; Homologous series.
    • Isomerism: structural and stereoisomerism.
    • Nomenclature (Trivial and IUPAC): Covalent bond fission Homolytic and heterolytic: free radicals, carbocations, and carbanions; stability of carbocations and free radicals, electrophiles, and nucleophiles.
  • Electronic displacement in a covalent bond: Inductive effect, electromeric effect, resonance, and hyperconjugation.
  • Common types of organic reactions: Substitution, addition, elimination, and rearrangement

Chapter 21 – Hydrocarbons

    • Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties, and reactions.
    • Alkanes: Conformations; Sawhorse and Newman projections (of ethane); Mechanism of halogenation of alkanes.
    • Alkenes: Geometrical isomerism.
  • Mechanism of electrophilic addition: addition of Hydrogen, halogens, water, hydrogen halides (Markownikoff’s and peroxide effect); Ozonolysis, oxidation, and polymerisation
    • Alkynes: Acidic character; Addition of Hydrogen, halogens, water, and hydrogen halides; Polymerisation.
    • Aromatic hydrocarbons: Nomenclature, benzene structure and aromaticity.
  • Mechanism of electrophilic substitution: halogenation, nitration, Friedel Crafts alkylation and acylation, directive influence of the functional group in monosubstituted benzene.

Chapter 22 – Organic Compounds Containing Halogens

    • General methods of preparation, properties, and reactions.
    • Nature of C-X bond.
  • Mechanisms of substitution reactions. 
  • Uses, Environmental effects of chloroform, iodoform, freons, and DDT

Chapter 23 – Organic Compounds Containing Oxygen

    • General methods of preparation, properties, reactions, and uses.
    • Alcohols: Identification of primary, secondary, and tertiary alcohols; mechanism of dehydration.
    • Phenols: Acidic nature, electrophilic substitution reactions: halogenation, nitration, and sulphonation, Reimer Tiemann reaction.
    • Ethers: Structure.
    • Aldehyde and Ketones: Nature of carbonyl group; Nucleophilic addition to >C=O group, relative reactivities of aldehydes and ketones.
    • Important reactions such as Nucleophilic addition reactions (addition of HCN, NH3 and its derivatives), Grignard reagent; oxidation; reduction (Wolff Kishner and Clemmensen); the acidity of Hydrogen, aldol condensation, Cannizzaro reaction, Haloform reaction.
    • Chemical tests to distinguish between aldehydes and Ketones.
  • Carboxylic Acids: Acidic strength and factors affecting it.

Chapter 24 – Organic Compounds Containing Nitrogen

    • General methods of preparation, properties, reactions, and uses.
  • Amines: Nomenclature, classification, structure, basic character and identification of primary, secondary, and tertiary amines and their basic character.
  • Diazonium Salts: Importance in synthetic organic chemistry.

Chapter 25 – Polymers

    • General introduction and classification of polymers, general methods of polymerisation addition and condensation, co-polymerisation.
  • Natural and synthetic rubber and vulcanisation. 
  • Some important polymers with emphasis on their monomers use polyethene, nylon, polyester, and bakelite.

Chapter 26 – Biomolecules

    • General introduction and importance of biomolecules.
    • Carbohydrates: Classification: aldoses and ketoses; monosaccharides (glucose and fructose), constituent monosaccharides or oligosaccharides (sucrose, lactose, maltose) and polysaccharides (starch, cellulose, glycogen).
    • Proteins: Elementary Idea of amino acids, peptide bond, polypeptides; Proteins: primary, secondary, tertiary, and quaternary structure (qualitative idea only), denaturation of proteins, enzymes.
  • Vitamins: Classification and functions. 
  • B Chemical constitution of DNA and RNA. Biological functions of nucleic acids.

Chapter 27 – Chemistry in Everyday Life

    • Chemicals in medicines: Analgesics, tranquillisers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamines, their meaning and common examples.
  • Chemicals in food: Preservatives artificial sweetening agents are common examples.
  • Cleansing agents: Soaps and detergents, cleansing action.

Chapter 28 – Principles Related to Practical Chemistry

  • Detection of extra elements (N, S, halogens) in organic compounds.
  • Detection of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl and amino groups in organic compounds.
  • The chemistry involved in the preparation of the following: Inorganic compounds: Mohr’s salt, potash alum, and Organic compounds: Acetanilide, p-nitro acetanilide, aniline yellow, iodoform.
  • The chemistry involved in the titrimetric exercises: Acids bases and the use of indicators, oxalic-acid vs KMnO4, Mohr’s salt vs KMnO4.
  • Chemical principles involved in the qualitative salt analysis: Cations: Pb2+, Cu2+, AI3+, Fe3+, Zn2+, Ni2+, Ca2+, Ba2+, Mg2+, NH4+, and Anions: CO32-, S2-, SO42-, NO2-, NO3-, CI-, Br, I. (Insoluble salts excluded).  
  • Chemical principles involved in the following experiments: Enthalpy of solution of CuSO4, Enthalpy of neutralisation of strong acid and strong base, preparation of lyophilic and lyophobic sols, and Kinetic study of the reaction of iodide ion with hydrogen peroxide at room temperature.

JEE Main Chemistry Syllabus- Topic-wise Weightages: 

The JEE Main Chemistry syllabus is very vast. It generally takes a lot of effort and time to search for and comprehend the essential topics. Therefore, Extramarks has brought you the high-to-low weightage of the topics that may have higher chances of appearing in the JEE Main 2023 exam.

For JEE Main Chemistry, there are theory-based questions. These questions are less time-consuming as compared to Chemistry and Mathematics questions. Although complex, questions on chemistry topics can boost your marks in JEE Main Exam, as this section is usually the easiest. Given below is a weightage table for various chapters. This weightage is provided as per the trends in the past.

Topics # Of Questions Marks
Transition Elements and Coordination Chemistry 3 12
Chemical Kinetics 1 4
Atomic Structure 1 4
Chemical Bonding 2 8
Alkyl Halides 1 4
Solid-State And Surface Chemistry 1 4
Nuclear Chemistry And Environment 2 8
Redox Reaction 1 4
Electrochemistry 1 4
Thermodynamics And Gaseous State 2 8
General Organic Chemistry 1 4
Stereochemistry 1 4
Chemical And Ionic Equilibrium 2 8
Hydrocarbon 1 4
Carboxylic Acid and their Derivatives 1 4
Periodic table and Representative Elements 2 8
Carbohydrates, amino acid and Polymers 1 4
Aromatic Compounds 1 4

JEE Main Chemistry Syllabus – Important Topics:

From JEE Main Organic Chemistry From JEE Main Inorganic Chemistry From JEE Main Physical Chemistry
Some more important topics in JEE Main organic chemistry are

• Reactions and their mechanism

• Acidity

• Nomenclature

• Basicity

In JEE Main, while all the chapters carry equal weightage, and it is important to clear each topic’s fundamentals, it is also important to primarily focus on the following, which are the most questioned of these topics.

• Methods of Preparation and Chemical Reactions, uses, etc., of the compounds.

• Chemical bonding

• Elements of the periodic table

• Transition elements and coordination chemistry

• S & P block elements and Hydrogen

• Dipole Moment

• Shape and Hybridisation

• Molecular Orbital Theory

• Fajan’s Rule & its application

• Mole concept is the most crucial topic for the JEE Main Physical Chemistry section. This is because specific reactions like Redox Reaction are based on the Mole concept. Hence, being the primary connection, this topic should be clear.

• Atomic Structure – Important formulas and basic concepts. JEE Main often has many questions from this chapter. 

• Important topics – Wavelength of Electronic Transition, Quantum Numbers, and Ionisation Energy.

• States of matter, Solid-state 

• van der Waals equation, Kinetic Theory of Gases, Types of Molecular Velocity 

Why is it important for candidates to  attempt Chemistry first in JEE Main exam?

Academic experts have long advised students to start with Chemistry while attempting the JEE Main paper. Few reasons for the same are:

  • A significant portion of the JEE Main Chemistry syllabus is based on fact-based knowledge. Many questions are also based on factual knowledge, and therefore students can quickly solve these problems. The extra time left after Chemistry can be better utilised for the Mathematics and Physics section.
  • Most top students are able to complete the JEE Main Chemistry section in a maximum of 40-45 minutes, giving ample time for the other two sections.
  • This is the advisable order to solve questions during exams within the Chemistry section. Start with questions of Inorganic Chemistry (budget 6-8 mins), followed by Organic Chemistry (budget 12-15 mins), and finally attend the Physical Chemistry questions (budget 15-17 mins). The rest of the time, you will have to solve the 5 numerical problems.

JEE Main Chemistry Syllabus – Best Books

Getting the right set of textbooks for the JEE Main Physics syllabus is an important step towards your overall JEE preparation.

NCERT Chemistry syllabus is comprehensive and covers all important topics for the JEE Main Chemistry syllabus. Read and practice from NCERT textbooks and NCERT Exemplar Problems to score well in the Chemistry section.

Along with NCERT preparation, below list of books are recommended by academic experts and past students for preparing for the JEE Main Chemistry subject:

  • Modern Approach to Chemical Calculations by R C Mukherjee
  • Organic Chemistry by O P Tandon
  • Concept of Physical Chemistry by P Bahadur
  • Concise Inorganic Chemistry by J D Lee
  • Physical Chemistry by P.W. Atkins 
  • Arihant’s Practice Book Chemistry for JEE Main And Advanced by R.K Gupta
  • Physical Chemistry by N Awasthi
  • Organic Chemistry by Solomons and Fryhle
  • University Chemistry Freedman and Young
  • Elementary problems in Organic Chemistry by MS Chauhan
  • Organic Chemistry by Morrison & Boyd

Exam Pattern of JEE Main Paper 1

Knowing about the exam pattern will help the candidates prepare as they will get to know what type of questions will be asked in the examination. Here is the JEE Main Paper Type-1 examination pattern:

  • Mode of Examination – Online (Computer-based)
  • Duration of Examination – 3 hours
  • Subject – Chemistry
  • Maximum Number of Questions – 25 questions 
  • Types of Questions – 20 Multiple Choice Questions + 5 numerical-based questions to be answered from a total of 10 Numerical questions 
  • Total Marks – 100 marks
  • Languages used in the ExaminationEnglish, Assamese, Bengali, Gujarati, Hindi, Kannada, Malayalam, Marathi, Odia, Punjabi, Tamil, Urdu, and Telugu.
  • Marking Scheme 
For MCQs For Numerical Based Questions
Four marks for correct answers Four marks for correct answers
-1 mark for incorrect answer No Negative Marking
0 marks for unattempted questions 0 marks for the wrong answer

JEE Main Chemistry Syllabus Preparation Tips:

JEE Main Chemistry Syllabus preparation tips for excelling in Physical Chemistry

For Physical Chemistry, thorough practice is most important. So you should keep a good set of books with lots of questions as part of your Chemistry study resources. You can safely rely on NCERT textbooks. Be careful when referring to other books, as they might contain additional topics that are not part of the official JEE Main Chemistry syllabus. You can refer to books from  RC Mukherjee, OP Tandon, N. Avasthi as they have a good set of problems. 

  • Students love Physical Chemistry because it does not require intense memorisation of chemical reactions and formulas. It involves various calculations, so experts advise students to keep practising to excel in Physical Chemistry. 
  • Chapters from NCERT Class 12 will have more weightage than Class 11. Two questions usually come from topics such as Solutions, Chemical Kinetics, Solid State, Atomic Structure in each JEE Main exam. Questions on Ionic Equilibrium, Thermodynamics, and Electrochemistry are found to be a bit tough. So practise these topics more.
  • Class 11 Physical Chemistry chapters are more challenging than class 12 chapters. Ionic Equilibrium, Thermodynamics, and Electrochemistry are the most difficult topics and require a clear understanding of theoretical concepts along with lots of question-solving practice. 
  • Class 12 chapters such as Solutions,  Solid State, Chemical Kinetics are easy, and students should master these topics to score fully in these questions. However, the chapter on Electrochemistry is tricky and requires theoretical and practical knowledge in the exam. Refer N. Avasthi for practising questions on this topic. 
  • Don’t miss out on Surface Chemistry. It’s a completely theory-oriented chapter, and you will surely get one question directly from the NCERT textbook in both JEE Main and JEE Advanced examinations.

JEE Main Chemistry preparation tips for excelling in Organic Chemistry

  • One-third of the JEE Main Chemistry questions come from Organic Chemistry chapters. Students should pay equal attention to both class 11 and 12 syllabus as the weightage is identical for both.
  • Students who have proper conceptual knowledge about these topics tend to solve the Organic Chemistry section faster, even if a few questions might appear a bit tricky. Many students face challenges in MCQs as they have a vague understanding of the topic and often get confused in multiple options. Experts advise students to fully understand JEE Main Chemistry syllabus from NCERT textbooks and solve complete exercises after each chapter. Many questions come directly from NCERT, and students can score quickly. 
  • Having a solid understanding of General Organic Chemistry at the start of the JEE Main Chemistry Syllabus is crucial. The conceptual understanding, including the mechanisms and exceptions covered in this topic, becomes the base in all the later Organic Chemistry chapters. 
  • Concepts from Acidity, Basicity, and Resonance are also required in many other JEE Main Chemistry syllabus chapters. So prepare these topics thoroughly and solve multiple question papers involving problems to determine the order of acids and bases.
  • Few topics are straightforward to understand and score good marks with less preparation time. These chapters are Chemistry in Everyday Life, Biomolecules and Polymers, and Classification of Elements in Organic Compounds.
  • Knowledge of topics and concepts around Mechanisms of Reactions and the reagents used in the reactions is important. Also, the topic of Aromatic Compounds and their reactions is important. It has been observed that these reaction-based questions come in both JEE Main and JEE Advanced question papers. So preparing well can help you score higher marks.
  • One important tip that has worked for many students is to prepare a list of exceptional behaviours of reactants, reagents and substrates after completing every chapter. This list will help you revise and memorise key elements from all chapters of your JEE Main Chemistry syllabus. Make a habit of solving Organic Chemistry questions for 30 – 45 minutes in your daily study routine. 

JEE Main Chemistry Syllabus preparation tips for excelling in Inorganic Chemistry

  • Class 12 Chemistry has 50% of chapters from Inorganic Chemistry. Inorganic Chemistry from the JEE Main Chemistry syllabus involves memorising various facts and exceptions versus understanding core concepts. This makes it difficult for students to prepare, and it generally gets neglected compared to Organic Chemistry.
  • More than half the paper has questions coming from Inorganic Chemistry. Experts advise students to have a strategy to help them revise Inorganic Chemistry concepts and exceptions daily. This will help them prepare better and score better against other candidates participating in the exam.
  • You can rely on NCERT textbooks for JEE Main Chemistry syllabus and have 2-3 more reference books. JEE Main exam toppers suggest books from J.D. Lee and OP Tandon. For problem-solving, you should refer to VK Jaiswal’s book “Problems in Inorganic Chemistry.
  • Considering that a lot has to be memorised, the study plan and revision strategy should be similar. Based on your liking, you can either use highlighters to mark important sections or keep a notebook where you jot down important points, reactions, exceptions, etc., for your revision later. Many students have found the use of sticky notes also to be helpful. Whichever strategy you use, the idea is for you to quickly browse through the critical points during your daily JEE Main Chemistry syllabus revision routine. 
  • Solving past problems is always beneficial. Keeping notes while solving problems will help you better understand the exam and question pattern. 
  • Create sheets and charts with a list of all essential reactions and exceptions from redox chapters, periodic tables, salt analysis, etc. Put them up on a wall to continuously see and memorise them.
  • Regular study is crucial for developing strength in Inorganic Chemistry. Don’t leave this section for the last moment. A simple plan is to daily study the chapters taught in your school and then utilise weekends to revise the same chapters.
  • Once you have completed the JEE Main Chemistry syllabus, start with 1 hour of revision for Inorganic Chemistry chapters, emphasising reactions and exceptions memorisation every day. Later it will start taking less time, around 30-45 min. Many questions come from reactions and exceptions, so cover this section adequately to score higher marks.

Other Generic  JEE Main Preparation Tips:=

  • Keep in mind the JEE Main syllabus.
  • Solve questions of higher levels from good books.
  • Analyse and solve as many previous years’ JEE Main question papers as possible.
  • Attend mock tests regularly, possibly one per week.
  • Be thorough with NCERT.
  • Regular revision of the previously studied JEE Main concepts is essential to prevent losing touch with concepts.
  •  Keep your resources limited.
  • Understand the JEE Main question paper pattern and prepare a pre-examination strategy.
  • Having a positive attitude is very important for success in the JEE Main exam. 
  • Maintaining a healthy lifestyle while preparing for JEE Main will give a healthy outlook towards life and enhance mental stability. 
  • Keeping aside some time every day for self-study is of crucial importance.

Benefits of Solving JEE Main Question Paper

  • Students can develop a fair understanding of JEE Main by solving the question paper with solutions.
  • Solving past years’ JEE Main papers helps students understand the JEE Main exam pattern.
  •  Students who solve past years’ papers are more likely to perform well in exams.
  • Solving the JEE Main question paper helps students boost speed and accuracy.
  • The JEE Main question papers help in improving time management.
  • Analysis of the JEE Main question paper will help familiarise students with the exam pattern and help score better marks. 

Guidelines for the Day of the Exam

  • Candidates should go to the examination centre one day in advance. They should familiarise themselves with the place, time taken to travel, etc., so that they are adequately familiar and have no problems with the date of exams.
  • They should plan to reach the examination hall one hour earlier on the exam date. Getting to the exam centre an hour earlier helps avoid last-minute issues. 
  • Candidates should carry a hard copy of their JEE Main admit card and a valid photo I.D. proof (PAN Card, Driving Licence, Voter ID, Passport, Aadhaar Card with Photograph, E-Aadhar, Ration Card, Aadhaar Enrolment Number with Photo).
  • No electronic devices, jewellery, watches, and so on are allowed into the exam hall. 

Do’s and Don’ts for JEE Main Exam

Given below are the do’s and don’ts for the JEE Main exam. 

Do’s:

  • Read each question very carefully to ensure a clear understanding, as students often misinterpret questions.
  • Start the question paper by attempting the more straightforward and medium questions of the JEE Main question paper first, which will help boost the candidate’s morale and help in increasing the JEE Main score. 
  • If you get a tricky and time-consuming question, please move to the next question, and translate that, as there is a similar marking for all questions. You can come back to solve the slightly tricky questions once all easy questions are solved.
  • Candidates are advised to carry their transparent water bottles and transparent ballpoint pen.

Don’ts:

  • The candidates are advised not to solve questions in haste as many silly mistakes occur.
  • Anxiety during the Exam is a significant factor and brings down students’ scores. 
  • Wearing uncomfortable clothes during exams will decrease the productivity of the candidate.

SYLLABUS for JEE (Main)-2022
Syllabus for Paper-1 (B.E./B.Tech.)- Chemistry

CHEMISTRY

PHYSICAL CHEMISTRY

UNIT I: SOME BASIC CONCEPTS IN CHEMISTRY

Matter and its nature, Dalton’s atomic theory: Concept  of  atom,  molecule,  element,  and compound: Physical quantities and their measurements  in  Chemistry,  precision,  and accuracy, significant figures. S.I.Units, dimensional analysis:  Laws  of  chemical  combination;  Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae: Chemical equations and stoichiometry.

UNIT 2: STATES OF MATTER

Classification of matter into solid, liquid, and gaseous states.

Gaseous State:

Measurable properties of gases: Gas laws – Boyle’s law, Charle’s law. Graham’s law of diffusion. Avogadro’s law, Dalton’s law of partial pressure; Concept of Absolute scale of temperature; Ideal gas equation; Kinetic theory of gases (only postulates); Concept of average, root mean square and most probable velocities; Real gases, deviation from Ideal behaviour,   compressibility   factor, and   van   der Waals equation.

Liquid State:

Properties of liquids – vapour pressure, viscosity and surface tension, and effect of temperature on them (qualitative treatment only).

Solid State:

Classification of solids: molecular, ionic, covalent and   metallic   solids,   amorphous   and   crystalline solids (elementary idea); Bragg’s Law and its applications: Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell parameters, an imperfection in solids; Electrical and magnetic properties.

UNIT 3: ATOMIC STRUCTURE

Thomson and Rutherford atomic models and their limitations; Nature of electromagnetic radiation, photoelectric  effect;  Spectrum  of  the  hydrogen atom.   Bohr   model   of  a   hydrogen   atom   –   its postulates, derivation of the relations for the energy of the electron and radii of the different orbits, limitations of Bohr’s model; Dual nature of matter, de Broglie’s relationship. Heisenberg uncertainty principle. Elementary ideas of quantum mechanics, quantum mechanics, the quantum mechanical model of  the  atom,  its  important  features.  Concept  of atomic orbitals as one-electron wave functions: Variation of Y and Y2 with r for 1s and 2s orbitals; various

quantum  numbers  (principal,  angular  momentum, and magnetic quantum numbers) and their significance; shapes of s, p, and d – orbitals, electron spin and spin quantum number: Rules for filling electrons in orbitals – Aufbau principle. Pauli’s exclusion principle and Hund’s rule, electronic configuration of elements, extra stability of half- filled and completely filled orbitals.

UNIT 4: CHEMICAL BONDING AND MOLECULAR STRUCTURE

Kossel   –   Lewis   approach   to   chemical   bond formation, the concept of ionic and covalent bonds.

Ionic Bonding: Formation  of ionic bonds, factors affecting the formation of ionic bonds; calculation of lattice enthalpy.

Covalent Bonding: Concept of electronegativity. Fajan’s rule, dipole moment: Valence Shell Electron Pair Repulsion (VSEPR ) theory and shapes of simple molecules.

Quantum mechanical approach to covalent bonding: Valence bond  theory – its important features, the concept of hybridization involving s, p, and d orbitals; Resonance.

Molecular Orbital Theory – Its important features. LCAOs, types of molecular orbitals (bonding, antibonding), sigma and pi-bonds, molecular orbital electronic configurations of homonuclear diatomic molecules, the concept of bond order, bond length, and bond energy.

Elementary idea of metallic bonding. Hydrogen bonding and its applications.

UNIT 5: CHEMICAL THERMODYNAMICS

Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes.

The first law of thermodynamics – Concept of work, heat internal energy and enthalpy, heat capacity,   molar   heat   capacity;   Hess’s   law   of constant heat summation; Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition, hydration, ionization, and solution.

The second law of thermodynamics – Spontaneity of processes; DS of the universe and DG of the system as criteria for spontaneity.   DG° (Standard Gibbs energy change) and equilibrium constant.

UNIT 6: SOLUTIONS

Different methods for expressing the concentration of solution – molality, molarity, mole fraction, percentage (by volume and mass both), the vapour pressure of solutions and Raoult’s Law – Ideal and non-ideal solutions, vapour pressure – composition, plots for ideal and non-ideal solutions; Colligative properties of dilute solutions – a relative lowering of vapour pressure, depression of freezing point, the elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar mass, van’t Hoff factor and its significance.

UNIT 7: EQUILIBRIUM

Meaning of equilibrium, the concept of dynamic equilibrium.

Equilibria involving physical processes: Solid- liquid, liquid – gas and solid-gas equilibria, Henry’s law.  General  characteristics  of  equilibrium involving physical processes.

Equilibrium involving chemical processes: Law of chemical equilibrium, equilibrium constants (Kp and Kc) and their significance, the significance of DG and DG° in chemical equilibrium, factors affecting equilibrium concentration, pressure, temperature, the effect of catalyst; Le Chatelier’s principle.

Ionic  equilibrium:  Weak and strong electrolytes, ionization of electrolytes, various concepts of acids and bases (Arrhenius. Bronsted – Lowry and Lewis) and their ionization, acid-base equilibria (including multistage ionization) and ionization constants, ionization of water. pH scale, common ion effect, hydrolysis of salts and  pH of their solutions, the solubility of sparingly soluble salts and solubility products, buffer solutions.

UNIT 8:  REDOX REACTIONS  AND ELECTROCHEMISTRY

Electronic  concepts  of  oxidation  and  reduction, redox   reactions,   oxidation   number,   rules   for assigning oxidation number, balancing of redox reactions.

Electrolytic and metallic conduction, conductance in electrolytic solutions, molar conductivities and their variation with concentration: Kohlrausch’s law and its applications.

Electrochemical cells – Electrolytic and Galvanic cells, different types of electrodes, electrode potentials  including  standard  electrode  potential, half – cell and cell reactions, emf of a Galvanic cell and its measurement: Nernst equation and its applications;  Relationship  between  cell  potential and Gibbs’ energy change: Dry cell and lead accumulator; Fuel cells.

UNIT 9: CHEMICAL KINETICS

Rate of a chemical reaction, factors affecting the rate of reactions: concentration, temperature, pressure, and catalyst; elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units, differential and integral forms of zero and first-order reactions, their characteristics and half-lives, the effect of temperature on the rate of reactions, Arrhenius theory,   activation   energy   and   its   calculation, collision  theory  of  bimolecular  gaseous  reactions (no derivation).

UNIT 10: SURFACE CHEMISTRY

Adsorption- Physisorption and chemisorption and their characteristics, factors affecting adsorption of gases   on   solids   –   Freundlich   and   Langmuir adsorption isotherms, adsorption from solutions.

Catalysis  –   Homogeneous   and   heterogeneous, activity and  selectivity of solid catalysts,  enzyme catalysis, and its mechanism.

Colloidal  state-  distinction  among true solutions, colloids, and suspensions, classification of colloids – lyophilic. lyophobic; multi-molecular. macromolecular and associated colloids (micelles), preparation and properties of colloids – Tyndall effect.  Brownian  movement,  electrophoresis, dialysis, coagulation, and flocculation: Emulsions and their characteristics.

INORGANIC CHEMISTRY

UNIT  11:  CLASSIFICATION  OF  ELEMENTS  AND PERIODICITY IN PROPERTIES

Modem  periodic  law  and  present  form  of  the periodic table, s, p. d and f block elements, periodic trends in properties of elements atomic and ionic radii, ionization enthalpy, electron gain enthalpy, valence, oxidation states, and chemical reactivity.

UNIT 12: GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF METALS

Modes   of   occurrence   of   elements   in   nature, minerals, ores; Steps involved in the extraction of metals – concentration, reduction (chemical and electrolytic methods), and refining with special reference to the extraction of Al. Cu, Zn, and Fe; Thermodynamic and electrochemical principles involved in the extraction of metals.

UNIT 13: HYDROGEN

Position of hydrogen in periodic table, isotopes, preparation, properties and uses of hydrogen; Physical and chemical properties of water and heavy water; Structure, preparation, reactions, and uses of hydrogen  peroxide;  Classification  of  hydrides  – ionic, covalent, and interstitial; Hydrogen as a fuel.

UNIT   14:   S   BLOCK   ELEMENTS   (ALKALI   AND ALKALINE EARTH METALS)

Group -1 and 2 Elements

General introduction, electronic configuration, and general trends in physical and chemical properties of  elements,   anomalous  properties  of  the  first element of each group, diagonal relationships.

Preparation and properties of some important compounds – sodium carbonate and sodium hydroxide  and  sodium  hydrogen  carbonate; Industrial uses of lime, limestone. Plaster of Paris and cement: Biological significance of Na, K. Mg, and Ca.

UNIT 15: P- BLOCK ELEMENTS

Group -13 to Group 18 Elements

General Introduction:   Electronic   configuration and general trends in physical and chemical properties of elements across the periods and down the groups; unique behaviour of the first element in each group.

Groupwise study of the p – block elements

Group -13

Preparation, properties, and uses of boron and aluminum; Structure, properties, and uses of borax, boric acid, diborane, boron trifluoride, aluminum chloride, and alums.

Group -14

The tendency for catenation; Structure, properties, and uses of Allotropes and oxides of carbon, silicon tetrachloride, silicates, zeolites, and silicones.

Group -15

Properties and uses of nitrogen and phosphorus; Allotrophic forms of phosphorus; Preparation, properties,  structure,  and  uses  of ammonia,  nitric acid, phosphine, and phosphorus halides, (PCl3. PCl5); Structures of oxides and oxoacids of nitrogen and phosphorus.

Group -16

Preparation,   properties,   structures,   and   uses   of ozone: Allotropic forms of sulphur; Preparation, properties, structures, and uses of sulphuric acid (including its industrial preparation); Structures of oxoacids of sulphur.

Group-17

Preparation, properties, and uses of hydrochloric acid;  Trends  in  the  acidic  nature  of  hydrogen halides; Structures of Interhalogen compounds and oxides and oxoacids of halogens.

Group-18

Occurrence and uses of noble gases; Structures of fluorides and oxides of xenon.

UNIT 16: d – and f- BLOCK ELEMENTS

Transition Elements

General introduction, electronic configuration, occurrence and characteristics, general trends in properties of the first-row transition elements – physical properties, ionization enthalpy, oxidation states, atomic radii, colour, catalytic behaviour, magnetic properties, complex formation, interstitial compounds,  alloy  formation;  Preparation, properties, and uses of K2Cr2O7, and KMnO4.

Inner Transition Elements

Lanthanoids – Electronic configuration, oxidation states, and lanthanoid contraction.

Actinoids – Electronic configuration and oxidation states.

UNIT 17: CO-ORDINATION COMPOUNDS

Introduction to coordination compounds. Werner’s theory; ligands, coordination number, denticity. chelation; IUPAC nomenclature of mononuclear co- ordination  compounds,  isomerism;  Bonding- Valence bond approach and basic ideas of Crystal field theory, colour and magnetic properties; Importance of co-ordination compounds (in qualitative  analysis,  extraction  of  metals  and  in biological systems).

UNIT 18: ENVIRONMENTAL CHEMISTRY

Environmental  pollution  –  Atmospheric,  water, and soil.

Atmospheric    pollution    –    Tropospheric and Stratospheric

Tropospheric pollutants – Gaseous pollutants: Oxides of carbon, nitrogen, and sulphur, hydrocarbons; their sources, harmful effects, and prevention; Greenhouse effect and Global warming: Acid rain;

Particulate pollutants: Smoke, dust, smog, fumes, mist; their sources, harmful effects, and prevention.

Stratospheric pollution- Formation and breakdown of ozone, depletion of the ozone layer – its mechanism and effects.

Water Pollution – Major pollutants such as. pathogens, organic wastes, and chemical pollutants; their harmful effects and prevention.

Soil pollution – Major pollutants such as; Pesticides (insecticides. herbicides and fungicides), their harmful effects, and prevention. Strategies to control environmental pollution.

ORGANIC CHEMISTRY

UNIT 19: PURIFICATION AND CHARACTERISATION OF ORGANIC COMPOUNDS

Purification – Crystallization, sublimation, distillation, differential extraction, and chromatography – principles and their applications.

Qualitative analysis – Detection of nitrogen, sulphur, phosphorus, and halogens.

Quantitative analysis (basic principles only) – Estimation of carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus.

Calculations of empirical  formulae and  molecular formulae: Numerical problems in organic quantitative analysis,

UNIT  20:SOME  BASIC  PRINCIPLES  OF  ORGANIC CHEMISTRY

Tetravalency of carbon: Shapes of simple molecules

– hybridization (s and p): Classification of organic compounds based on functional groups: and those containing halogens, oxygen, nitrogen, and sulphur; Homologous series: Isomerism – structural and stereoisomerism.

Nomenclature (Trivial and IUPAC)

Covalent bond fission – Homolytic and heterolytic: free radicals, carbocations, and carbanions; stability of carbocations and free radicals, electrophiles, and nucleophiles.

Electronic displacement in a covalent bond

–  Inductive  effect,  electromeric  effect,  resonance, and hyperconjugation.

Common types of organic reactions- Substitution, addition, elimination, and rearrangement.

UNITS 21: HYDROCARBONS

Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties, and reactions.

Alkanes – Conformations: Sawhorse and Newman projections (of ethane): Mechanism of halogenation of alkanes.

Alkenes  –  Geometrical isomerism: Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides (Markownikoffs and  peroxide  effect):  Ozonolysis  and polymerization.

Alkynes – Acidic character: Addition of hydrogen, halogens, water, and hydrogen halides: Polymerization.

Aromatic hydrocarbons – Nomenclature, benzene – structure  and  aromaticity:  Mechanism  of electrophilic substitution: halogenation, nitration.

Friedel – Craft’s alkylation and acylation, directive influence of the functional group in mono- substituted benzene.

UNIT   22:   ORGANIC   COMPOUNDS   CONTAINING HALOGENS

General methods of preparation, properties, and reactions; Nature of C-X bond; Mechanisms of substitution reactions.

Uses;  Environmental  effects  of  chloroform, iodoform freons, and DDT.

UNIT   23:   ORGANIC   COMPOUNDS   CONTAINING OXYGEN

General  methods  of  preparation,  properties, reactions, and uses.

ALCOHOLS, PHENOLS, AND ETHERS

Alcohols: Identification of primary, secondary, and tertiary alcohols: mechanism of dehydration.

Phenols: Acidic nature, electrophilic substitution reactions: halogenation. nitration and sulphonation. Reimer – Tiemann reaction.

Ethers: Structure.

Aldehyde and Ketones: Nature of carbonyl group; Nucleophilic addition to >C=O group, relative reactivities of aldehydes and ketones; Important reactions such as – Nucleophilic addition reactions (addition   of   HCN.   NH3,   and   its   derivatives), Grignard  reagent;  oxidation:  reduction  (Wolf Kishner and Clemmensen); the acidity of a- hydrogen. aldol condensation, Cannizzaro reaction. Haloform reaction, Chemical tests to distinguish between aldehydes and Ketones.

Carboxylic Acids

Acidic strength and factors affecting it,

UNIT 24: ORGANIC COMPOUNDS CONTAINING NITROGEN

General methods of preparation. Properties, reactions, and uses.

Amines: Nomenclature, classification structure, basic character, and identification   of   primary,   secondary, and tertiary amines and their basic character.

Diazonium Salts: Importance in synthetic organic chemistry.

UNIT 25: POLYMERS

General introduction and classification of polymers, general methods of polymerization, – Addition and condensation, copolymerization.

Natural and synthetic, rubber and vulcanization, some important polymers with emphasis on their monomers and uses – polythene, nylon, polyester, and bakelite.

UNIT 26: BIOMOLECULES

General introduction and importance of biomolecules.

CARBOHYDRATES  –   Classification;   aldoses and   ketoses:   monosaccharides   (glucose and fructose) and constituent monosaccharides of oligosaccharides (sucrose, lactose, and maltose).

PROTEINS – Elementary Idea of a-amino acids,  peptide  bond,  polypeptides. Proteins: primary, secondary, tertiary, and quaternary  structure  (qualitative  idea only), denaturation of proteins, enzymes.

VITAMINS  –  Classification  and functions.

NUCLEIC  ACIDS  –  Chemical constitution of DNA and RNA.

Biological functions of nucleic acids.

UNIT 27: CHEMISTRY IN EVERYDAY LIFE

Chemicals in Medicines – Analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, anti-fertility drugs, antibiotics, antacids. Anti-histamines -their meaning and common examples.

Chemicals  in  food  –  Preservatives, artificial sweetening agents – common examples.

Cleansing  Agents  –  Soaps  and detergents, cleansing action

UNIT 28: PRINCIPLES RELATED  TO PRACTICAL CHEMISTRY

Detection of extra elements (Nitrogen, Sulphur, halogens) in organic compounds; Detection of the following functional groups; hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketones) carboxyl, and amino groups in organic compounds.

  • The chemistry involved  in  the preparation  of the following:

Inorganic compounds; Mohr’s salt, potash alum. Organic       compounds:       Acetanilide,       p-nitro acetanilide, aniline yellow, iodoform.

  • The chemistry involved in the titrimetric exercises – Acids, bases and the use of indicators, oxalic-acid vs KMnO4, Mohr’s salt vs KMnO4
  • Chemical principles involved in the qualitative salt analysis:

Cations – Pb2+, Cu2+, Al3+, Fe3+, Zn2+, Ni2+,Ca2+, Ba2+, Mg2+, NH+

Anions- CO2− , S2-, SO2− , NO3-, NO2-, Cl- 3,  4

Br-, I- ( Insoluble salts excluded).

Chemical    principles    involved    in    the    following experiments:

  1. Enthalpy of solution of CuSO4
  2. Enthalpy of neutralization of strong acid and strong base.
  3. Preparation of lyophilic and lyophobic sols.
  4. Kinetic study of the reaction of iodide ions with hydrogen peroxide at room temperature.

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FAQs (Frequently Asked Questions)

1. Is JEE Main Chemistry tough?

Chemistry is generally the easiest and most scoring of the papers of JEE Main. Most of the students score high in Chemistry, and this is because most of the questions are direct, and there are almost no calculations. The questions from Organic Chemistry may be a little bit tricky but not tough. Inorganic chemistry is mostly theory and is asked directly but requires a good amount of memorising reactions and exceptions.

2. Which chapters are there in the JEE Main Chemistry syllabus?

The JEE Main Chemistry syllabus has been covered in detail in this article. Scroll above, and you will get all details, including chapter wise topic details, chapter/topic weightage, syllabus preparation tips, etc.

3. Is Organic Chemistry important for JEE Main?

Yes, all three sections of Chemistry hold equal weightage. Organic Chemistry is as vital as Inorganic Chemistry or Physical Chemistry.

4. Do NCERT textbooks cover the whole JEE Main Chemistry syllabus?

Yes, JEE Main Chemistry Syllabus is mapped from the NCERT syllabus of classes 11th and 12th.

5. How can one score 250 plus marks in JEE Main 2023?

To score 250 plus marks in JEE Main 2023 requires a lot of focus, rigorous preparation, and some of the following tips should help:

  • One must study each topic without skipping any topic.
  • Students must have a clear and good understanding of the syllabus, questioning patterns, essential topics, topics that are most repeated and they must practise based on a regular timetable.  
  • Allocate a good amount of time for revision.
  • Memorise all the important reactions and exceptions.
  • Practise the last few years’ question papers and regularly take mock tests.

6. Can I give JEE without Chemistry?

No, you cannot apply for JEE Main without the Chemistry subject. JEE Main consists of three subjects: Physics, Chemistry, and Mathematics. And all subjects are compulsory.

 

7. What is the number of questions in the JEE Main Chemistry paper?

The JEE Main Chemistry paper has 20 MCQs and 10 Numerical Questions. However, only 5 out of 10 numericals must be answered. Each correct answer will get you +4 marks, and you get -1 for incorrect answers. No negative marking exists for numerical questions. This paper has a maximum marks of 100.

 

8. What are the critical topics in the JEE Main Chemistry Syllabus?

JEE Main Chemistry syllabus has three crucial and broad parts: Physical, Organic and Inorganic Chemistry. Refer to the above sections of this article, and you will get topic-wise and chapter-wise details for JEE Main Chemistry syllabus.

9. Why choose Extramarks to crack JEE Main Chemistry 2023?

Extramarks has wonderful resources for JEE Main and JEE Advanced preparation. Please browse our website to get free access to resources that you can refer to and include in your primary study resources. We have resources on JEE Main question papers, JEE Advanced question papers, JEE Main mock tests, JEE Main revision notes for each subject and chapter, JEE Main sample papers. Our expert academic team has created answer keys with solutions to help students understand the relevant answers with concepts and chapter knowledge.

JEE aspirants can use these essential solutions as a self-assessment tool. They can first solve the questions by themselves and then compare their responses to those provided by our experts. This will help them understand their preparedness and the correct method to solve. This process will allow them to learn time management skills and understand the correct pattern and right marking scheme. Thus, they will be better prepared to score well in the JEE Main exams with all the above benefits.

 

10. How to include past years’ JEE Main question papers in your study plan?

Including previous years’ question papers, sample papers and taking mock tests is very important in a student’s study plan.

First, get access to all past years’ papers from the Extramarks website, especially the last ten years. Put up a plan so that you can solve one paper daily. Make it a habit, and do not skip it for any reason.

Make notes of all the wrong answers by subject/chapter/topic. Then, refer to book chapters and JEE Main 2021 question paper with solutions to learn the correct solution. That way, you will understand and strengthen new concepts you are currently missing.

In the last month of examination, increase your rigour and pace. Mimic natural exam environment and strictly adhere to the time duration of exams.

11. Is NCERT enough for JEE, and especially for JEE Main Chemistry syllabus?

The JEE Main exam is critical in the life of those that aspire to do engineering in India. This is so because there are limited seats, and the JEE Main Syllabus is vast. Moreover, the JEE Examinations are based on the syllabus of NCERT, and often, questions from NCERT books appear in the JEE Main exam. Therefore, those that have practised well and are thorough with the basic concepts from NCERT should have a high ability to solve most questions with a high level of accuracy.

The official syllabus of JEE Main entrance exam is similar to the one given in NCERT textbooks, and hence NCERT books are essential for JEE Main preparations. Moreover, the syllabus of JEE Main and that of CBSE’s Class 11 and 12 board is almost the same. Therefore, students can consider NCERT books as they are one of the best reference materials.

However, this does not mean that NCERT books are enough. Students must use the NCERT as their essential study guide. They should be well versed and thorough with the NCERT books and subsequently use the other recommended books for higher-order exam preparation. 

JEE Main Chemistry syllabus is vast but easy and scoring if candidates practise adequately. Aspirants can undoubtedly do very well with a good understanding of the JEE Main Chemistry syllabus and good preparation.